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1. Atomic Theory and Periodicity

2. Nomenclature

3. Quantitative Chemistry

4. Chemical Bonding

5. Intermolecular Forces

6. Solutions

7. Redox Reactions

8. Thermodynamics

9. Equilibrium

10. Gases

11. Solids

12. Phase Diagrams

13. Electrochemistry

14. Acids and Bases

15. Kinetics

16. Nuclear Chemistry

17. Organic Chemistry

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Copyright © 2009 AP Chem Solutions
1. Atomic Theory and Periodicity

1.1 The Histroy of Atomic Theory
Venus Flytrap, Democritus, Lavoisier I, Lavoisier II, Proust, Dalton, J. J. Thompson, Rutherford
Separation of Alpha, Beta, and Gamma
, Rutherford Gold Foil I, Rutherford Gold Foil II, Millikan

1.2 Isotopes and Average Atomic Mass
Atomic Number, Mass Number, and Number of Neutrons; Atomic Number, Mass Numbers and
Isotopes
, Ex1) Average Atomic Mass from % Abundances, Ex2) Average Atomic Mass from %
Abundances
, Ex1) % Abundance from Average Atomic Mass, Ex2) % Abundance from Average
Atomic Mass I
, Ex2) % Abundance from Average Atomic Mass II

1.3 Waves
Ex1) Calculating Wavelength, Ex2) Calculating Frequency

1.4 Quantum Theory
Planck, Photoelectric Effect, Ex) E = hv Problem

1.5 Atomic Emission Spectrum
ElectroMagnetic Spectrum, Hydrogen Emission Spectum, Atomic Spectrums, Atomic Spectrums
Animation
, Flame Test Demo, Ex) Energy Quantization in Hydrogen Problem

1.6 DeBroglie Wave Equation
Ex1) DeBroglie Wave Equation

1.7 Quantum Numbers
s-Orbilal Animation, px-Orbilal Animation, py-Orbilal Animation, pz-Orbilal Animation, d-Orbital
Animation I
, d-Orbital Animation II, d-Orbital Animation III, d-Orbital Animation IV, d-Orbital
Animation V
, The Four Quantum Numbers, Ex) Valid Sets of Quantum Numbers

1.8 Electron Configuration and Orbital Diagrams
Orbitals and Electron Configuration I (Kahn Academy), Electron Configuration II (Kahn Academy),
Electron Configuration III (Kahn Academy), Electron Configuration, Electron Configuration of Ions

1.9 Periodicity
Effective Nuclear Charge, Atomic Radii I, Atomic Radii II, Ionic Radii (Khan Academy), Ionic Radii;
Ionization Energy Concept, Ionization Energy Trend, Electron Affinity Concept, Electron Affinity Trend,
Electronegativity,
Ionization Energy (Khan Academy); 2nd Ionization Energy, Electromegativity, and Atomic Radii (Khan
Academy)

2. Nomenclature

2.1 Naming Ionic Compounds, Ionic Formulas, and Hydrates
Naming Simple Ionic Compounds and Ionic Formulas I, Naming Simple Ionic Compounds and Ionic
Formulas II
, Naming Simple Ionic Compounds and Ionic Formulas III, Naming Metalic Compounds I,
Naming Metalic Compounds II, Naming Metalic Compounds III, Naming Compounds with Polyatomic
Ions I
, Naming Compounds with Polyatomic Ions II, Naming Compounds with Polyatomic Ions III

2.2 Naming Covalent Compounds and Molecular Formulas
Naming Molecular Compounds I, Naming Molecular Compounds II, Naming Molecular Compounds
III

2.3 Naming Acids
Naming Acids

3. Quantitative Chemistry

3.1 Molecular Weight and Mass Percent
Ex1) Mass % Composition, Ex2) Mass % Composition, Ex3) Mass % Composition, Ex4) Percent
Composition of Water in a Hydrate

3.2 The Mole
The Mole Concept and Avogadro's Number, The Mole Concept and Avogadro's Number (Kahn
Academy)
, Ex1) Molar Mass Calculations, Ex2) Molar Mass Calculation

3.3 Mole to Mole Problems
Balancing Chemical Equations, Ex1) Mole to Mole Problems, Ex2) Mole to Mole Problem

3.4 Mass to Mass Problems
Mass to Mass Stoichiometry Explained, Ex1) Mass to Mass Problem, Ex2) Mass to Mass Problems

3.5 Limiting Reactant Problems
Limiting Reactant Concept, Limiting Reactant Animation, Ex1) Limiting Reactant, Ex2) Limiting
Reactant
, Ex3) Limiting Reactant, Ex4) Limiting Reactant

3.6 Empirical and Molecular Formulas
Empirical and Molecular Formulas (Khan Academy), Ex1) Empirical Formula from Mass%, Ex2)
Empirical Formula from Mass%
, Ex1) Empirical Formula from Mass Data, Ex1) Molecular Formula
from MM and Empirical Formula
, Ex2) Molecular Formula from MM and Empirical Formula

4. Chemical Bonding

4.1 Ionic and Covalent Bonding
Ionic Bonding (MR), Covalent Bonding (MR), Ionic and Covalent Bonding (Khan Academy),
Electrolytic Solutions Animation, Lattice Energy

4.2 Lewis Structures
Lewis Structures I, Lewis Structures II

4.3 Exceptions to the Octet Rule
Lewis Structures (Expanded Octets)

4.4 Formal Charge
Ex) Calculating Formal Charge

4.5 Resonance Structures
Resonance I, Resonance II

4.6 VSEPR I
The Geometries that Result from 2, 3, and 4 Charge Clouds; 2 Charge Clouds Animation; 3 Charge
Clouds Animation
; 4 Charge Clouds Animation

4.7 VSEPR II
The Geometries that Result from 5 and 6 Charge Clouds; 2, 3, 4, 5, and 6 Charge Clouds Animation;
Square Planar Animation; Amination of all Shapes

4.8 Valence Bond Theory and Hybrid Orbital Theory
Valence Bond Theory, sp Hybrid Orbitals Animation; sp2 Hybrid Orbitals Animation; sp3 Hybrid
Orbitals Animation
; sp, sp2, and sp3 Hybridization Animation, sp, sp2, sp3, sp3d, and sp3d2
Animation
, Sigma and Pi Bond Animation

4.9 Polar and Non-Polar Molecule
Polar and Non-Polar Bonds, Polar and Non-Polar Molecules, Ex1) Polar and Non-Polar Molecules,
Ex2) Polar and Non-Polar Molecules, Ex3) Polar and Non-Polar Molecules, Ex4) Polar and
Non-Polar Molecules

5. Intermolecular Forces

5.1 Types of Intermolecular Forces
London Dispersion and Dipole Dipole Forces, Hydrogen Bonds I, Hydrogen Bonds II, Hydrogen
Bonds III
, Hydrogen Bonds IV, Ion Dipole, and Ion Induced Dipole Forces

6. Solutions

6.1 Types of Solutions
Types of Solutions

6.2 Expressing Concentration
Ex1) Molarity, Ex2) Molarity, Ex1) Molality

6.3 Solubility and Precipitation Reactions
Solubilty Concept, Solutions and Solubility, Dissolution of NaCl Animation I, Dissolution of NaCl
Animation II
, Dissolution of Potassium Permanganate Animation, Solubility Tables, Ex1) Net Ionic
Equations

6.4 Factors Affecting Solubility, Solubility Curves and Supersaturated Solutions
Factors Affecting Solubility (Solubility and Structure), Factors Affecting Solubility (Structure, Pressure,
and Temperature)
, Solubility Curves and Supersturated Solutions, Supersaturated Solutions Demo I,
Supersaturated Solutions Demo II

6.5 Factors Affecting the Solubility of Gases
Henry's Law Animation, Gas Solubility and Temperature

6.6 Colligative Properties
Introduction to Colligative Properties, Freezing Point Depression, Vapor Pressure Reduction and
Boiling Point Elevation (Concepts and Example Problems)
, Ex) Boiling Point Elevation and Freezing
Point Depression
, Osmosis, Osmosis and Osmotic Pressue, Ex) Osmotic Pressure

7. Redox Reactions

7.1 Redox Reactions and Oxidation Numbers
Oxidation Numbers Concept, Rules for Assigning Oxidation Numbers, Ex) Assigning Oxidation
Numbers
, Oxidation of Zinc, Redox Reaction, Redox Reactions, Ex) Redox Reactions, Oxidizing and
Reducing Agents

7.2 Balancing Redox Reactions in Acidic and Basic Solutions
Writing Half-Reactions, Ex 1) Balancing Redox Reactions in Acidic Solutions, Ex2) Balancing Redox
Reactions in Acidic Solutions
, Ex) Balancing Redox Reactions in Basic Solutions I, Ex) Balancing
Redox Reactions in Basic Solutions II

7.3 The Activity Series and Types of Redox Reactions
Writing Chemical Equations for Combustion, Decomposition, and Single Replacement Reactions with
Demos
, Hydrogen Displacement Reaction Demo, Zinc Oxide Reaction, Formation of Solid Ag Demo,
Combustion of Elements Demo, Combustion of Zinc Animation

8. Thermodynamics

8.1 Endothermic / Exothermic Reactions and Enthalpy
Enthalpy and Enthalpy Change, Thermochemical Equations, Endothermic/Exothermic Reaction, and
Enthalpy

8.2 Average Bond Enthalpy
Ex1) Enthalpy Change from Average Bond Enthalpies, Ex2) Enthalpy Change from Average Bond
Enthalpies

8.3 Calorimetry
Ex1) Calorimetry Equation, Ex2 Calorimetry Equation, Ex3) Calorimetry Equation

8.4 Hess' Law
Ex1) Hess' Law and State Function, Ex2) Hess' Law, Ex3) Hess' Law, Ex4) Hess' Law, Ex5 Hess'
Law

8.5 Enthalpy of Formation
Ex1) Enthalpy of Formation Problem and Concept, Ex2) Enthalpy of Formation Problem and Concept,
Thermite Reaction Demo

8.6 Enthalpy of Vaporization and Enthalpy of Fusion
Changes of State (Khan Academy), Changes of State (MR), Changes of State Animation, Vapor
Pressure (Khan Academy)
, Vapor Pressure, Vapor Pressure (MR)

8.7 Entropy
Spontaneous Reactions and Entropy, Ex) Entropy, Air Bag Animation

8.8 Free Energy
Free Energy, Ex1) Free Energy, Ex2) Free Energy, Ex3) Free Energy

9. Equilibrium

9.1 Dynamic Equilibrium and the Equilibrium Expression
Phase Labels, Dynamic Equilibrium, Dynamic Equilibrium Animation, The Equilibrium Expression

9.2 The Pressure Constant and Equilibrium Position
Kp vs. Kc

9.3 Calculating Equilibrium Concentrations and Partial Pressures
Ex1) Finding Equilibrium Concentrations, Ex2) Finding Equilibrium Concentrations, Ex3) Finding
Equilibrium Concentrations (Quadratic Equation)


9.4 The Reaction Quotient
The Reaction Quotient, Ex) Reaction Quotient

9.5 Le Chatelier's Principle
Changing Concentration, Temperature and Pressure (Khan Academy), Le Chatelier's Principle,
Changing Concentration and Temperature Demo), Changing Pressure Demo, Le Chatelier's Principle
Animation

9.6 Manipulating Equilibrium Constants
Ex1) Manipulating Keq, Ex2) Manipulating Keq

9.7 The Solubility Product Constant and Predicting Precipitates
The Solubility Product Constant and Molar Solubility, Ex1) Ksp Problems, Ex2) Ksp Problems, Ex1)
Predicting Precipitates

9.8 Free Energy and Equilibrium
Free Energy and Equilibrium

10. Gases

10.1 Pressure, Kinetic Molecular Theory, Boyle's Law, Charles Law, and Combined Gas Law
Pressure, Kinetic Molecular Theory, Boyle's Law I, Boyle's Law II, Boyle's Law III, Boyle's Law IV,
Charles Law I, Charles Law II, Charles Law III Balloon in Liquid Nitrogen, Charles Law IV Balloon in
Liquid Nitrogen
, Gas Laws Animation, Ex1) Combined Gas Law, Ex2) Combined Gas Law

10.2 Avogadro's Principle and STP
Ex) Avogadro's Principle and STP

10.3 Ideal Gas Law
Ideal Gas Law Concept, Ideal Gas Law Animation, Ex1) Ideal Gas Law, Ex2) Ideal Gas Law, Ex3
Ideal Gas Law
, Ex4) Ideal Gas Law, Ex5) Ideal Gas Law, Ex6) Ideal Gas Law (Find the Molar Mass)

10.4 Dalton's Law of Partial Pressure and Collecting Gas over Water
Dalton's Law of Partial Pressure: Concept and Problems (MR), Dalton's Law and Mole Fractions

10.5 Mole Fractions and Partial Pressures
Ex1) Mole Fractions and Partial Pressures Problems

10.6 Average Kinetic Energy and Speed of a Gas
Average KE Animation, Average Speed of a Gas, Gas Speed Animation

10.7 Effusion and Diffusion
Effusion and Diffusion Concept and Problems, Effusion Animation

10.8 Real vs. Ideal Gases
Real vs. Ideal Gases and the Van der Waals Equation

11. Solids

11.1 Unit Cells, Molecular Solids, Covalent Network Solids, and Metallic Solids
Unit Cells, Simple Cubic Structure Animation I, Simple Cubic Structure Animation II, Body Centered
Cubic Structure |Animation I
, Body Centered Cubic Structure Animation II, Face Centered Cubic Unit
Cells
, Face Centered Cubic Structure Animation, Covalent Network, Ionic, and Metalic Solids,
Covalent Network Bonding of Diamond and Graphite, Structure of Graphite and Diamond Animation

12. Phase Diagrams

12.1 Phase Diagrams
Phase Diagrams I, Phase Diagrams II

13. Electrochemistry

13.1 Voltaic Cells and Standard Cell Potentials
Spontaneous Redox Reactions and Voltaic Cells (demo), Voltaic Cells (MR), Voltaic Cells (Khan
Academy)
, Voltaic Cell Animation I, Voltaic Cell Animation II, Voltaic Cell Animation III, Voltage and
Standard Cell Potentials
, Ex) Standard Cell Potentials

13.2 Spontaneous Redox Reactions and Free Energy
Free Energy and Redox Reactions

13.3 Nernst Equation and Concentration Cells
The Nernst Equation and Concentration Cells

13.4 Electrolytic Cells
Electrolysis of Molten NaCl and LiF, Electrolysis of Water, Electroplating, Ex) Electrolysis
Calculations
, Ex) Quantitative Electrolysis

14. Acids and Bases

14.1 Defining Acids and Bases
Arrhenius Acids and Bases, Bronsted Lowry Acids and Bases, Bronsted Lowry Animation, Lewis
Acids and Bases
, Lewis Acid Base Animation

14.2 Strengths of Acids and Bases
Strengths of Acids and Bases, Strong and Weak Bases Animation, Strong and Weak Acids Animation
I
, Strong and Weak Acids Animation II

14.3 Acid and Base Dissociation Constants
Ka, Kb and the Strengths of Acids and Bases, Ka of a Weak Acid Animation, Autoionization of
Water
, Kw, Ex1) Kw Problems, Ex2) Kw Problems, Autoionization of Water Animation

14.4 The pH of Strong Acids and Bases
Introduction to pH, pH of Strong Acids and Bases, Ex) pH of Strong Acids, Ex) pOH of Strong Base,
Ex) Conversions between pH and pOH

14.5 Calculating the pH of Weak Acids
Ex1) pH of a Weak Acid, Ex2) pH of a Weak Acid, Ex3) pH of a Weak Acid

14.6 Calculation the pH of Weak Bases
Ex1) pH of a Weak Base

14.7 Reactions of Acids and Bases
Neutralization Reaction Animation

14.8 Soluble Salts and pH
14.9 The Common Ion Effect
Common Ion Effect Concept and Problem, Ex) Common Ion Effect, Common Ion Effect Animation,
Common Ion Effect Demo

14.10 Buffered Solutions
The Buffer Concept, Buffer Animation I, Buffer Animation II, Ex1) Buffer Solutions, Ex2) Buffer
Solutions I
, Ex2) Buffer Solutions II, Ex3) Buffer Solutions, Ex4) Buffer Solution I, Ex4) Buffer
Solutions II
,

14.11 Solubility and pH
Solubility and pH, Slightly Soluble Ionic Compounds in Strong Acid Solutions Animation

14.12 Complex Ion Formation
Complex Ion Formation

14.13 Acid Base Titrations
Strong Acid Strong Base Titrations Concept, Strong Acid Strong Base Titration Curves, Weak Acid
Strong Base Titration Concept
, Titration Curves Review, Ex1) Acid Base Titration Problems, Ex2)Acid
Base Titration Problems
, Ex3) Acid Base Titration Problem, Ex4) Acid Base Titration Problems, Acid
Base Titration Animation
, Titration Laboratory Techniques

15. Kinetics

15.1 Reaction Rates, Order of Reactions, and Rate Laws
Introduction to Reaction Rates and Rate Laws, Ex) Determining Rate Laws with Experimental Data

15.2 Integrated Rate Laws
Half Life for 1st Order Reactions Concept, Ex) Half Life for 1st Order Reactions

15.3 Factors Affecting Reaction Rates and Activation Energy
Factors Affecting Reaction Rates, Concentration and Reaction Rate Demo, Collision Orientation
Animation I
, Collision Orienation Animation II, Collision Orientation Animation III, Energy Diagram and
Collision Orientation Animation
, Activation Energy Animation

15.4 Reactions Mechanisms and Catalysis
Reaction Mechanisms Introduction, Reaction Mechanisms Advanced, Ex1) Reaction Mechanisms, The
Ozone Layer
, Catalytic Destruction of Ozone by NO Animation, Catalytic Destruction of Ozone by Cl
Animation
, Rate Determining Step Demo

16. Nuclear Chemistry

16.1 Modes of Nuclear Decay
Atomic Number, Mass Number, and Number of Neutrons; Alpha Decay, Beta Decay and Positron
Emission
; Alpha Decay, Beta Decay, and Gamma Rays Animation; Ex 1) Alpha Decay, Ex2) Electron
Capture
; Ex3) Electron Capture, Ex) Writing Nuclear Decay Equations

16.2 Configurations for Nuclear Stability
Configuratons of Nuclear Stability

16.3 Half Life
The Concept of Half-Life, The Concept of Half Life (MR), Ex1) Half-Life Problems, Ex2) Half Life,
Ex3) Half Life

16.4 Nuclear Fission and Fusion
Nuclear Fission, Nuclear Fusion I, Nuclear Fusion II, Nucrear Fusiom III, Nuclear Fission and Fusion

17. Organic Chemistry

17.1 Naming Alkanes and Structural Isomerism
Naming the First 10 Alkanes, Side Groups I, Side Groups II, Naming Alkanes with Side Groups I,
Naming Alkanes with Side Groups II, Naming Alkanes with Side Groups III, Naming Cycloalkanes

17.2 Naming Alkenes, Alkynes, and Aromatic Compounds
Naming Alkenes and Alkynes I, Naming Alkenes and Alkynes II, Cis and Trans Isomers, Naming
Aromatic Compounds

17.3 Naming Functional Groups
Alcohols, Ethers, Aldehydes, Ketones, Carboxylic Acids, Ester, Amines, Amides

17.4 Reactions of Hydrocarbons
Substitution Reactions, Combustion Reactions, Addition Reactions I, Addition Reactions II

17.5 Reactions of Functional Groups
Dehydration Reactions, Etherificationa and Esterification, Esterification, Preparing Aldehydes and
Ketones I
, Preparing Aldehydes and Ketones II


High School Chem Solutions e-Textbook

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